The molecular structure of [{SbEtBr(μ-Br)[SCN(Me)C₂Me₂N(Me)]}₂}
Black, Steven J., Jones, Cameron, and Junk, Peter C. (2001) The molecular structure of [{SbEtBr(μ-Br)[SCN(Me)C₂Me₂N(Me)]}₂}. Main Group Metal Chemistry, 24 (7). pp. 453-454.
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Abstract
[Extract] Prior to this work there were no crystallographically characterised examples of imidazolethione adducts of organoantimony compounds and only 3 exaamples of imidazolethione adducts of antimony trihalides [1-3]. The antimony centre in the present compound has a slightly distorted square based pyramidal geometry and a stereochemically active lone pair. The compound sits on an inversion centre and is dimeric thorugh unsymmetrical Sb-Br-Sb bridges, both the longer and shorter interactions of which oie in the normal region for SB-Br bonds [4]. The geometry of the imidazolethione ligand in the complex is similar to its geometry in the uncoordinated state [5].
| Item ID: | 13306 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 0792-1241 |
| Keywords: | main group chemistry; X-ray crystallography |
| Additional Information: | Reproduced with permission from the journal: Main Group Metal Chemistry. The final publication is available at www.degruyter.com |
| Date Deposited: | 02 Nov 2012 02:28 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030204 Main Group Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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