Green photochemistry: photo-Friedel–Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids
Murphy, Brian, Goodrich, Peter, Hardacre, Christopher, and Oelgemöller, Michael (2009) Green photochemistry: photo-Friedel–Crafts acylations of 1,4-naphthoquinone in room temperature ionic liquids. Green Chemistry, 11 (11). pp. 1867-1870.
![[img]](https://researchonline.jcu.edu.au/style/images/fileicons/application_pdf.png) |
PDF (Published Version)
Restricted to Repository staff only |
Abstract
The photo-Friedel–Crafts acylation of 1,4-naphthoquinone with various aldehydes was investigated in a series of room temperature ionic liquids. High conversions and selectivities were achieved in [C2mim]+-based ionic liquids with the highest isolated yields found in [C2mim][NTf2]. The developed procedure allowed for a replacement of hazardous solvents such as benzene and acetonitrile which are commonly used for this transformation.
| Item ID: | 9904 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1463-9270 |
| Date Deposited: | 08 Apr 2010 05:54 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Downloads: |
Total: 4 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |