New divalent and trivalent lanthanoid complexes from lanthanoid pseudo-Grignard reagents and exploration into their reaction chemistry
Halim, Md Abdul (2025) New divalent and trivalent lanthanoid complexes from lanthanoid pseudo-Grignard reagents and exploration into their reaction chemistry. PhD thesis, James Cook University.
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Abstract
MD Abdul Halim examined the synthesis and characterisation of pseudo-Grignard complexes from the reactivity of pseudo-Grignard reagents. This trapping method yielded LnII [Ln(DippForm)Br(thf)3]2 6thf (Sm, Eu) and LnIII [Ln(L)I2(solv)n] (Ln = La, Ce, Nd, Sm, Er, Lu; L = DippForm, XylForm, Ph2pz, solv = thf; L = 4-tBu-PhO, solv = dme) complexes
| Item ID: | 94609 |
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| Item Type: | Thesis (PhD) |
| Keywords: | chemistry, trivalent lanthanoid complexes, divalent lanthanoid complexes, lanthanoid pseudo-Grignard reagents, reaction chemistry |
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| Copyright Information: | Copyright © 2025 Md Abdul Halim |
| Additional Information: | Four publications arising from this thesis are stored in ResearchOnline@JCU, at time of processing. Please see the Related URLS. The publications are: [Chapter 1] Halim, Md Abdul, Guo, Zhifang, Blair, Victoria L., Deacon, Glen B., and Junk, Peter C. (2024) Lanthanoid pseudo-Grignard reagents: A review. Journal of Organometallic Chemistry, 1010. 123094. [Chapter 2] Halim, Md Abdul, Guo, Zhifang, Deacon, Glen B., and Junk, Peter C. (2023) Bromobenzene Transforms Lanthanoid Pseudo-Grignard Chemistry. Chemistry - A European Journal, 29 (36). e202300956. [Chapter 3] Halim, Md Abdul, Guo, Zhifang, Blair, Victoria L., Deacon, Glen B., and Junk, Peter C. (2025) Syntheses of Pyrazolato- and Formamidinato-lanthanoid(III) Diiodides from in Situ Generated lanthanoid(III) Pseudo-Grignard Reagents. European Journal of Inorganic Chemistry, 28 (4). e202400672. [Chapter 5] Guo, Zhifang, Halim, Md Abdul, Blair, Victoria L., Deacon, Glen B., and Junk, Peter C. (2023) Direct Reaction – One Step Route to Synthesize Lanthanoid-iodide Formamidinates**. Chemistry: an Asian journal, 18 (14). e202300333. |
| Date Deposited: | 12 Nov 2026 04:47 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 28 EXPANDING KNOWLEDGE > 2801 Expanding knowledge > 280105 Expanding knowledge in the chemical sciences @ 100% |
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