Past fire severity and intensity identified in SE Australian sediments using boron isotopes and FTIR spectroscopy

Ryan, Rebecca, Lu, Shawn, Lemarchand, Damien, Thomas, Zoë, Simkovic, Ivan, Dlapa, Pavel, Worthy, Martin, Wasson, Robert, Bradstock, Ross, Haynes, Katharine, and Dosseto, Anthony (2025) Past fire severity and intensity identified in SE Australian sediments using boron isotopes and FTIR spectroscopy. Quaternary Science Reviews, 369. 109605.

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Abstract

Landscape-scale bushfires threaten lives, property, and biodiversity. Understanding how their characteristics have changed over time proves vital in improving management strategies and understanding future ecosystem responses. Therefore, there is an urgent need to develop novel proxies to extend our existing record of past fire characteristics, such as severity and intensity. Here, we use carbon and nitrogen contents, Fourier Transform Infrared (FTIR) spectroscopy, and boron isotopes in a sedimentary archive to investigate past fire events in Namadgi National Park (southeastern Australia) and estimate their characteristics such as fire intensity and severity. Strontium and neodymium isotopes were used to assess the possible catchment-scale erosion events following fire. The aromatic/aliphatic ratio of sediments showed that fire frequency and intensity have increased in the last 200 years compared to the previous 3000. Boron isotopes were influenced by both lithology and fire severity, where negative excursions may result from higher contributions of bark to mineral ash, whilst positive excursions in the isotope ratio result from higher contributions of leaves. Negative excursions in the B isotope ratio, coinciding with positive excursions in the aromatic/aliphatic ratio, were hypothesised to record low-severity fires that experienced longer residence times. This multi-proxy approach provides valuable insights into past fire characteristics. By improving our understanding of how fire characteristics have changed in the past, the results can inform mechanistic models to improve predictions of fire severity and intensity changes in the future.

Item ID: 87746
Item Type: Article (Research - C1)
ISSN: 1873-457X
Keywords: Fire, Fire intensity, FTIR spectroscopy, Isotopes, Southeastern Australia
Copyright Information: © 2025 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
Funders: Australian Research Council (ARC)
Projects and Grants: ARC DP200101123
Date Deposited: 03 Feb 2026 06:08
FoR Codes: 41 ENVIRONMENTAL SCIENCES > 4106 Soil sciences > 410604 Soil chemistry and soil carbon sequestration (excl. carbon sequestration science) @ 100%
SEO Codes: 18 ENVIRONMENTAL MANAGEMENT > 1806 Terrestrial systems and management > 180605 Soils @ 100%
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