Inherent helicity in an extended tris-bipyridyl molecular cage

Perkins, David F., Lindoy, Leonard F., Meehan, George V., and Turner, Peter (2004) Inherent helicity in an extended tris-bipyridyl molecular cage. Chemical Communications, 2. pp. 152-153.

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Abstract

A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(II) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends 22 along the axial length of the molecule.

Item ID: 860
Item Type: Article (Research - C1)
ISSN: 1364-548X
Date Deposited: 28 May 2010 03:25
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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