Inherent helicity in an extended tris-bipyridyl molecular cage
Perkins, David F., Lindoy, Leonard F., Meehan, George V., and Turner, Peter (2004) Inherent helicity in an extended tris-bipyridyl molecular cage. Chemical Communications, 2. pp. 152-153.
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DOI: 10.1039/b312716h
View at Publisher Website: http://dx.doi.org/10.1039/b312716h
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Abstract
A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(II) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends 22 along the axial length of the molecule.
| Item ID: | 860 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1364-548X |
| Date Deposited: | 28 May 2010 03:25 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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