Lanthanoid pseudo-Grignard reagents: A review
Halim, Md Abdul, Guo, Zhifang, Blair, Victoria L., Deacon, Glen B., and Junk, Peter C. (2024) Lanthanoid pseudo-Grignard reagents: A review. Journal of Organometallic Chemistry, 1010. 123094.
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Abstract
This review covers the progress of the chemistry of divalent lanthanoid pseudo-Grignard, compounds, with E-Ln-X bonding (E = C, N, O; X = I, Br, Cl, F), especially since the 2002 review of Petrov et al. (2002)[1]. Emphasis is on synthetic pathways and the structures of these compounds. Their use in oxidation and metathesis reactions is discussed together with a consideration of interactions with organic substrates. The compounds appear to have considerable untapped potential.
| Item ID: | 83611 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1872-8561 |
| Keywords: | Grignard reagents, Lanthanoids, Rare earths, Structures, Synthesis |
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| Copyright Information: | © 2024 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
| Date Deposited: | 11 Sep 2024 23:13 |
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