Lanthanoid pseudo-Grignard reagents: A review
Halim, Md Abdul, Guo, Zhifang, Blair, Victoria L., Deacon, Glen B., and Junk, Peter C. (2024) Lanthanoid pseudo-Grignard reagents: A review. Journal of Organometallic Chemistry, 1010. 123094.
|
PDF (Pubished Version)
- Published Version
Available under License Creative Commons Attribution. Download (815kB) | Preview |
Abstract
This review covers the progress of the chemistry of divalent lanthanoid pseudo-Grignard, compounds, with E-Ln-X bonding (E = C, N, O; X = I, Br, Cl, F), especially since the 2002 review of Petrov et al. (2002)[1]. Emphasis is on synthetic pathways and the structures of these compounds. Their use in oxidation and metathesis reactions is discussed together with a consideration of interactions with organic substrates. The compounds appear to have considerable untapped potential.
| Item ID: | 83611 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1872-8561 |
| Keywords: | Grignard reagents, Lanthanoids, Rare earths, Structures, Synthesis |
| Related URLs: | |
| Copyright Information: | © 2024 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). |
| Date Deposited: | 11 Sep 2024 23:13 |
| Downloads: |
Total: 19 Last 12 Months: 8 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |