Guo, Zhifang, Deacon, Glen B., and Junk, Peter C. (2024) When is a reported air-stable PrIV complex not a PrIV complex? Answer: when it is PrIII. Journal of Coordination Chemistry. (In Press)

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Abstract

All the data recently reported for the purported air/water stable PrIV complex, [(L)PrIV(L)4(OH0.94Cl0.06)2PrIV(L)]n (L = N-acetylanthranilate) [1], have been reinterpreted to show that it is, in fact, the PrIII complex [Pr2L6(H2O)2]n. Importantly, it is isomorphous with its reported EuIII analogue [Eu2L6(H2O)2]n [2], providing further evidence of the incorrect assignment in the literature.

Item ID:	83610
Item Type:	Article (Research - C1)
ISSN:	1029-0389
Keywords:	coordination chemistry, oxidation, Praseodymium, X-ray crystal structure
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Copyright Information:	© 2024 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group. This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives License (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial re-use, distribution, and reproduction in any medium, provided the original work is properly cited, and is not altered, transformed, or built upon in any way. The terms on which this article has been published allow the posting of the Accepted Manuscript in a repository by the author(s) or with their consent.
Date Deposited:	11 Sep 2024 22:51
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