Abazari, Reza, Sanati, Soheila, Bajaber, Majed A., Javed, Muhammad Sufyan, Junk, Peter C., Nanjundan, Ashok Kumar, Qian, Jinjie, and Dubal, Deepak P. (2023) Design and Advanced Manufacturing of NU-1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications. Small. 2306353. (In Press)

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Abstract

Metal–organic frameworks (MOFs) represent a relatively new family of materials that attract lots of attention thanks to their unique features such as hierarchical porosity, active metal centers, versatility of linkers/metal nodes, and large surface area. Among the extended list of MOFs, Zr-based-MOFs demonstrate comparably superior chemical and thermal stabilities, making them ideal candidates for energy and environmental applications. As a Zr-MOF, NU-1000 is first synthesized at Northwestern University. A comprehensive review of various approaches to the synthesis of NU-1000 MOFs for obtaining unique surface properties (e.g., diverse surface morphologies, large surface area, and particular pore size distribution) and their applications in the catalysis (electro-, and photo-catalysis), CO2 reduction, batteries, hydrogen storage, gas storage/separation, and other environmental fields are presented. The review further outlines the current challenges in the development of NU-1000 MOFs and their derivatives in practical applications, revealing areas for future investigation.

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