Hajiashrafi, Taraneh, Sheikholeslami, Mohaddeseh, Arjanaki, Maryam Ahmadi, Tarighi, Sara, Guo, Zhifang, and Junk, Peter C. (2023) Synthesis, structure analysis and catalytic activity of two Ln-coordination polymers containing benzophenone-4,4'-dicarboxylate linker. New Journal of Chemistry, 47 (5). pp. 2230-2239.

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Abstract

Two lanthanide-coordination polymers (Ln-CPs) containing benzophenone-4,4'-dicarboxylate (bpndc(2-)) linker, namely [Er-2(bpndc)(3)(DMF)(2)] (1) and [Yb-2(bpndc)(3)(DMF)(2)] (2) were synthesized and characterized using X-ray crystallography and spectroscopic methods. The topological analysis revealed that both compounds are chiral three-dimensional uninodal 5-connected net of type yfh. These Ln-CPs showed good stability and thus were used as heterogeneous catalysts for the acetalization of glycerol. This study provides some further evidence supporting the effectiveness of Ln-CPs as potential Lewis acid catalysts for chemical transformations.

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