Carbon bridged biphenolate ligands in rare earth chemistry

Shephard, Angus C.G., Ali, Safaa H., Deacon, Glen B., and Junk, Peter C. (2022) Carbon bridged biphenolate ligands in rare earth chemistry. New Journal of Chemistry, 46 (41). pp. 19612-19628.

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DOI: 10.1039/d2nj04358k

View at Publisher Website: https://doi.org/10.1039/d2nj04358k

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Abstract

Rare earth biphenolate species have become an increasingly studied series of complexes, owing to the diversity they offer over mononuclear aryloxide complexes, as well as their efficacy as catalysts and initiators in a range of organic transformations and polymerisation reactions. Compared to monodentate aryloxide ligands, biphenolate ligand systems are still in their infancy in rare earth coordination chemistry. In their limited use, the ligand 2,2 '-methylenebis(6-tert-butyl-4-methylphenol) (mbmpH(2)) has been a popular candidate. This review aims to highlight the chemistry that has been explored thus far with these carbon bridged lanthanoid biphenolate systems.


Item ID:	76636
Item Type:	Article (Research - C1)
ISSN:	1369-9261
Copyright Information:	© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2022. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
Funders:	Australian Research Council (ARC)
Projects and Grants:	ARC DP19010079
Date Deposited:	26 Oct 2022 09:09
FoR Codes:	34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100%
SEO Codes:	28 EXPANDING KNOWLEDGE > 2801 Expanding knowledge > 280105 Expanding knowledge in the chemical sciences @ 100%
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