Impact of Hydrogen Sulfide Scavenger Residuals on the Fluorescence Behaviour of OiW Discharges from Gas-Condensate Production

Lehmann, Marc, Vamvounis, George, Bloom, Sarah, Prout, Jake, Gordon-Wright, Henry, and Das, Sambit (2022) Impact of Hydrogen Sulfide Scavenger Residuals on the Fluorescence Behaviour of OiW Discharges from Gas-Condensate Production. In: Proceedings of the SPE Asia Pacific Oil & Gas Conference and Exhibition. From: SPE Asia Pacific Oil & Gas Conference and Exhibition, 17-19 October 2022, Adelaide, SA, Australia.

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Abstract

The oil-in-water (OiW) contaminants in produced water discharges arising from offshore oil and gasproduction systems are required by global regulatory bodies to be monitored in order to limit theenvironmental impacts of such releases. The level of these contaminants is commonly measured using onlineanalyzers that utilize UV fluorescence to target the luminescent properties of OiW components.

It is known that the nature and variability of the fluorophores in the OiW fractions may influence theresponse of these type of analyzers. In particular these readings can also be affected by chemical residualsused in oil and gas treatment, that may also be present in the produced water. This study reports on the impactof the reaction products of a monoethanolamine based hydrogen sulfide scavenger, used in gas treatmentto remove hydrogen sulfide (H2S), on the fluorescence behavior of OiW discharges, and its implications onthe OiW reporting levels that may be expected from deep-UV and near-UV based analyzers.

Item ID: 76626
Item Type: Conference Item (Presentation)
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Copyright Information: Copyright 2022, Society of Petroleum Engineers.
Date Deposited: 25 Oct 2022 00:30
FoR Codes: 41 ENVIRONMENTAL SCIENCES > 4104 Environmental management > 410402 Environmental assessment and monitoring @ 50%
34 CHEMICAL SCIENCES > 3406 Physical chemistry > 340699 Physical chemistry not elsewhere classified @ 50%
SEO Codes: 26 PLANT PRODUCTION AND PLANT PRIMARY PRODUCTS > 2601 Environmentally sustainable plant production > 260102 Management of liquid waste from plant production (excl. water) @ 100%
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