Serendipitous Formation of a Cerium(IV)-Mercury(II) Separated Ion Coordination Polymer#
Werner, Daniel, Deacon, Glen B., and Junk, Peter C. (2022) Serendipitous Formation of a Cerium(IV)-Mercury(II) Separated Ion Coordination Polymer#. Zeitschrift fuer Anorganische und Allgemeine Chemie, 648. e202200142.
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Abstract
Trivalent cerium tris-tert-butoxide, "[Ce(OtBu)(3)]", was synthesised in situ and treated with excess HgCl2. After reaction, colourless crystals were identified amongst excess HgCl2. Analysis by X-ray crystallography revealed the formation of an unusual ion separated coordination polymer consisting of two [Ce-IV(OtBu)(3)(thf)(3)](+) ions and a di-anionic chloridomercurate(II) two dimensional sheet [Hg8Cl18](2-), giving the overall formula [{Ce(OtBu)(3)(thf)(3)}(2){Hg8Cl18}](infinity) (1).
| Item ID: | 75133 |
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| Item Type: | Article (Research - C1) |
| ISSN: | 1521-3749 |
| Copyright Information: | © 2022 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. |
| Funders: | Australian Research Council (ARC) |
| Projects and Grants: | ARC DP190100798 |
| Date Deposited: | 22 Jun 2022 09:25 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 28 EXPANDING KNOWLEDGE > 2801 Expanding knowledge > 280105 Expanding knowledge in the chemical sciences @ 100% |
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