Evaluation of the relative importance of Ti–Cl⋯H–N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl2(NHMe2)2] (R = iPr, C6H5 or C6F5)
Adams, Nico, Cowley, Andrew R., Dubberley, Stuart R., Sealey, Andrew J., Skinner, Michael E. G., and Mountford, Philip (2001) Evaluation of the relative importance of Ti–Cl⋯H–N hydrogen bonds and supramolecular interactions between perfluorophenyl rings in the crystal structures of [Ti(NR)Cl2(NHMe2)2] (R = iPr, C6H5 or C6F5). Chemical Communications, 1 (24). pp. 2738-2739.
![[img]](https://researchonline.jcu.edu.au/style/images/fileicons/application_pdf.png) |
PDF (Published Version)
- Published Version
Restricted to Repository staff only |
Abstract
The three closely-related compounds [Ti(NiPr)Cl2(NHMe2)2] 1, [Ti(NC6H5)Cl2(NHMe2)2 ] 2 and [Ti(NC6F5)Cl2(NHMe2)2 ] 3 all crystallize in the space group C2/c with the titanium atoms lying on two-fold axes at (0, y, 1/4); in compounds 1 and 2 the molecules are linked in one-dimensional infinite chains by intermolecular Ti–Cl⋯H–N hydrogen bonds along the direction of the crystallographic c axis, whereas in 3 offset face-to-face interactions between the C6F5 rings break down the hydrogen bonded chains.
| Item ID: | 74862 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1364-548X |
| Copyright Information: | © The Royal Society of Chemistry 2001. |
| Date Deposited: | 09 Nov 2023 06:01 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340209 Organometallic chemistry @ 100% |
| SEO Codes: | 28 EXPANDING KNOWLEDGE > 2801 Expanding knowledge > 280105 Expanding knowledge in the chemical sciences @ 100% |
| Downloads: |
Total: 1 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |