Adams, Nico, Arts, Henricus J., Bolton, Paul D., Cowell, Dan, Dubberley, Stuart R., Friederichs, Nic., Grant, Craig M., Kranenburg, Mirko, Sealey, Andrew J., Wang, Bing, Wilson, Paul J., Cowley, Andrew R., Mountford, Philip, and Schröder, Martin (2004) Discovery and evaluation of highly active imidotitanium ethylene polymerisation catalysts using high throughput catalyst screening. Chemical Communications, 4. pp. 434-435.

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Abstract

A family of ca. 50 imidotitanium precatalysts [Ti(NR)(Me3[9]aneN3)Cl2] (R = alkyl or aryl; Me3[9]aneN3 = 1,4,7-trimethyltriazacyclononane) were prepared in good yields using semi-automated procedures; high-throughput screening techniques identified seven highly active ethylene polymerisation precatalysts with activities in the range ca. 3 400 to 10 000 kg(PE) mol−1 h−1 bar−1.

Item ID:	74857
Item Type:	Article (Short Note)
ISSN:	1364-548X
Copyright Information:	© Royal Society of Chemistry 2023.
Date Deposited:	14 Nov 2023 00:22
FoR Codes:	34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340209 Organometallic chemistry @ 90% 34 CHEMICAL SCIENCES > 3403 Macromolecular and materials chemistry > 340306 Polymerisation mechanisms @ 10%
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