Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes
Shephard, Angus C.G., Daniels, Daisy P., Deacon, Glen B., Guo, Zhifang, Jaroschik, Florian, and Junk, Peter C. (2022) Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes. Chemical Communications, 58. pp. 4344-4347.
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DOI: 10.1039/d2cc00698g
View at Publisher Website: https://doi.org/10.1039/d2cc00698g
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Abstract
The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C–P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.
| Item ID: | 73422 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1364-548X |
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| Copyright Information: | © The Royal Society of Chemistry 2022. |
| Date Deposited: | 06 Apr 2022 08:54 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 28 EXPANDING KNOWLEDGE > 2801 Expanding knowledge > 280105 Expanding knowledge in the chemical sciences @ 100% |
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