Metallo-supramolecular assemblies incorporating 1,3- and 1,4-aryl linked bis-beta-diketones - some recent studies

Clegg, J.K., Jolliffe, K.A., Lindoy, L.F., and Meehan, G.V. (2008) Metallo-supramolecular assemblies incorporating 1,3- and 1,4-aryl linked bis-beta-diketones - some recent studies. Polish Journal of Chemistry, 82 (6). pp. 1131-1144.

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Abstract

A review of recent work in the authors’ laboratories involving the interaction of 1,3- and 1,4-aryl linked bis-b-diketone derivatives with divalent and trivalent metal ions is presented. In some instances, bifunctional bridging ligands have been employed to extend the resulting structures from two to three dimensions. Examples of metallo-supra molecular dinuclear ‘platforms’, tetranuclear cofacial dimers, dinuclear helicates, trinuclear triangles, stepped metallo-polymers, a prismatic columnar polymer and large cavity-containing, tetranuclear tetrahedra are all discussed.

Item ID: 7038
Item Type: Article (Research - C1)
ISSN: 0137-5083
Keywords: supramolecular chemistry; beta-diketone; X-ray crystallography
Date Deposited: 05 Mar 2010 03:18
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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