Continuous-flow photochemical transformations of 1,4-naphthoquinones and phthalimides in a concentrating solar trough reactor

Yaseen, Madyan A., Mumtaz, Saira, Hunter, Richard L., Wall, Daniel, Robertson, Mark J., and Oelgemoeller, Michael (2020) Continuous-flow photochemical transformations of 1,4-naphthoquinones and phthalimides in a concentrating solar trough reactor. Australian Journal of Chemistry, 73 (12). pp. 1149-1157.

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DOI: 10.1071/CH20138

View at Publisher Website: https://doi.org/10.1071/CH20138

Abstract

A series of photochemical transformations has been successfully conducted under continuous-flow conditions in a concentrating solar trough reactor. Photoacylations and [2þ2]-photocycloadditions involving 1,4-naphthoquinones gave the corresponding photoproducts in moderate to high yields with residence times of 70 min. Likewise, acetone-sensitized photodecarboxylations involving phthalimides furnished the corresponding benzylated hydroxy phthalimidines in good to excellent yields and purity with residence times of 40 min. Compared with corresponding exposures to direct sunlight conducted in a solar float, flow operation generally gave superior conversions and subsequent yields.


Item ID:	65291
Item Type:	Article (Research - C1)
ISSN:	1445-0038
Keywords:	solar chemistry; flow photochemistry; photoacylation; photocycloaddition; photodecarboxylation
Copyright Information:	(C) CSIRO 2020
Additional Information:	The authors wish to advise of errors in the paper Aust. J. Chem. (2020) 73(12):1149-1157. Corrigendum to: Continuous-Flow Photochemical Transformations of 1,4-Naphthoquinones and Phthalimides in a Concentrating Solar Trough Reactor (Aust. J. Chem. (2020) 73(12):1149-1157). Australian Journal of Chemistry, 73 (12). p. 1301. DOI: 10.1071/CH20138_CO
Funders:	Australian Research Council (ARC)
Projects and Grants:	ARC Discovery Project (DP130100794)
Date Deposited:	11 Dec 2020 01:59
FoR Codes:	34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340503 Organic chemical synthesis @ 40% 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340504 Organic green chemistry @ 50% 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340505 Physical organic chemistry @ 10%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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