Photochemistry of phthalimides: photodecarboxylative addition of carboxylates and PET-induced macrocyclizations

Oelgemoeller, Michael (1999) Photochemistry of phthalimides: photodecarboxylative addition of carboxylates and PET-induced macrocyclizations. EPA Newsletters, 66 (July). pp. 63-64.

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Abstract

The main topics of this Thesis are inter-and intramolecular photoinitiated electron transfer reactions with thioethers and carboxylates as electron donating components. As electron acceptors aromatic imides such as phthalimides, trimellitic and quinolinic acid imides were used. The first Chapter deals with applications of intermolecular PET-additions of alkyl carboxylates, alpha-ketocarboxylates, as well as alpha-and beta-donorsubstituted alkyl carboxylates. The second Chapter deals with applications of intramolecular PET-cyclization reactions of omega-phthalimido thioethers, alkyl carboxylates and the corresponding alpha-and beta-donorsubstituted alkyl carboxylates. The alkyl chains which were used as linkers between electron donor and acceptor groups could be further functionalized by using ester or amide groups.

Item ID: 61389
Item Type: Article (Abstract)
ISSN: 1011-4246
Keywords: photochemistry; phthalimides; photodecarboxylations
Date Deposited: 15 Jun 2021 02:58
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 60%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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