Trapping CS₂²⁻ and S₃²⁻ between two ytterbium formamidinates

Werner, Daniel, Deacon, Glen B., and Junk, Peter C. (2019) Trapping CS₂²⁻ and S₃²⁻ between two ytterbium formamidinates. Inorganic Chemistry, 58 (3). pp. 1912-1918.

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Abstract

Treatment of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII2(DippForm)4(CS2)] (3) and [YbIII2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS22− dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.

Item ID: 57251
Item Type: Article (Research - C1)
ISSN: 1520-510X
Copyright Information: Copyright © 2019 American Chemical Society
Funders: Australian Research Council (ARC)
Projects and Grants: ARC Discovery DP 160101640
Date Deposited: 27 Feb 2019 07:48
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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