Trapping CS₂²⁻ and S₃²⁻ between two ytterbium formamidinates
Werner, Daniel, Deacon, Glen B., and Junk, Peter C. (2019) Trapping CS₂²⁻ and S₃²⁻ between two ytterbium formamidinates. Inorganic Chemistry, 58 (3). pp. 1912-1918.
![[img]](https://researchonline.jcu.edu.au/style/images/fileicons/application_pdf.png) |
PDF (Published Version)
- Published Version
Restricted to Repository staff only |
View at Publisher Website: https://doi.org/10.1021/acs.inorgchem.8b...
16
2
Abstract
Treatment of [YbII(DippForm)2(thf)n] (n = 2 (1aYb), n = 1 (1bYb); DippForm = N,N′-bis(2,6-diisopropylphenyl)formamidinate), with either excess CS2 or S8 gives [YbIII2(DippForm)4(CS2)] (3) and [YbIII2(DippForm)4(S2)0.5/(S3)0.5] (4) respectively. 3 is a new addition to an exclusive class of compounds containing the CS22− dianion, and 4 is the first crystallographically characterized example of a rare-earth trisulfide complex.
| Item ID: | 57251 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1520-510X |
| Copyright Information: | Copyright © 2019 American Chemical Society |
| Funders: | Australian Research Council (ARC) |
| Projects and Grants: | ARC Discovery DP 160101640 |
| Date Deposited: | 27 Feb 2019 07:48 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Downloads: |
Total: 2 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |