Rapid photochemical reaction studies under continuous-flow conditions in the Vapourtec UV-150 reactor - a technical note

Hunter, Richard, Josland, Sam, Moore, Joseph, Guthrie, Duncan, Robertson, Mark J., and Oelgemoeller, Michael (2018) Rapid photochemical reaction studies under continuous-flow conditions in the Vapourtec UV-150 reactor - a technical note. Current Organic Chemistry, 22. pp. 2501-2508.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: https://doi.org/10.2174/1385272822666181...
 
1


Abstract

Five different model reactions (photodecarboxylation, inter- and intramolecular [2+2] cycloadditions, TiO2 photocatalytic reduction and type II photooxygenation) were investigated in the advanced Vapourtec UV-150 photo reactor with their conversion and throughput potentials reported. Compared to known batch reactions in laboratory reactors, significantly higher calculated productivities were achieved despite a rather small 10 mL reactor coil. The device enables rapid, convenient, reliable and reproducible flow photochemistry studies across the entire wavelengths spectrum and on flexible scales.

Item ID: 56841
Item Type: Article (Research - C1)
ISSN: 1875-5348
Keywords: photochemistry, flow chemistry, capillary reactor, photodecarboxylation, photocycloaddition, TiO2 photocatalysis, photooxygenation
Funders: Australian Research Council (ARC), James Cook University (JCU)
Projects and Grants: ARC DP130100794, JCU RIBG 2014
Date Deposited: 15 Jan 2019 00:30
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 70%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 30%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 1
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page