Rapid photochemical reaction studies under continuous-flow conditions in the Vapourtec UV-150 reactor - a technical note
Hunter, Richard, Josland, Sam, Moore, Joseph, Guthrie, Duncan, Robertson, Mark J., and Oelgemoeller, Michael (2018) Rapid photochemical reaction studies under continuous-flow conditions in the Vapourtec UV-150 reactor - a technical note. Current Organic Chemistry, 22. pp. 2501-2508.
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Abstract
Five different model reactions (photodecarboxylation, inter- and intramolecular [2+2] cycloadditions, TiO2 photocatalytic reduction and type II photooxygenation) were investigated in the advanced Vapourtec UV-150 photo reactor with their conversion and throughput potentials reported. Compared to known batch reactions in laboratory reactors, significantly higher calculated productivities were achieved despite a rather small 10 mL reactor coil. The device enables rapid, convenient, reliable and reproducible flow photochemistry studies across the entire wavelengths spectrum and on flexible scales.
| Item ID: | 56841 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1875-5348 |
| Keywords: | photochemistry, flow chemistry, capillary reactor, photodecarboxylation, photocycloaddition, TiO2 photocatalysis, photooxygenation |
| Funders: | Australian Research Council (ARC), James Cook University (JCU) |
| Projects and Grants: | ARC DP130100794, JCU RIBG 2014 |
| Date Deposited: | 15 Jan 2019 00:30 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340503 Organic chemical synthesis @ 70% 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340505 Physical organic chemistry @ 30% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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