Recent advances in photodecarboxylations involving phthalimides

Mumtaz, Saira, Robertson, Mark J., and Oelgemoeller, Michael (2018) Recent advances in photodecarboxylations involving phthalimides. Australian Journal of Chemistry, 71 (9). pp. 634-648.

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Abstract

Owing to their favourable photophysical and electrochemical properties, phthalimides undergo a variety of highly efficient photodecarboxylation reactions. These transformations have been applied to the synthesis of macrocyclic compounds as well as bioactive addition adducts. N-Acetoxyphthalimides are versatile precursors to imidyl and alkyl radicals through photodecarboxylation and have subsequently been used for a variety of coupling reactions. The generally mild reaction conditions make these reactions attractive for green chemical applications. The process protocols were successfully transferred to novel photoreactor devices, among these falling film or continuous flow reactors.

Item ID: 55694
Item Type: Article (Research - C1)
ISSN: 1445-0038
Keywords: phthalimides; photodecarboxylation; flow photochemistry
Copyright Information: Copyright © CSIRO 2018
Funders: Australian Research Council (ARC), Higher Education Commission of Pakistan
Projects and Grants: ARC DP130100794, International Research Support Initiative Program
Date Deposited: 25 Sep 2018 23:48
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 70%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 30%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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