A deca-9-fluorenolato-deca-samarium oxide cage

Werner, Daniel, Deacon, Glen B., and Junk, Peter C. (2018) A deca-9-fluorenolato-deca-samarium oxide cage. European Journal of Inorganic Chemistry, 2018 (20-21). pp. 2241-2246.

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The 9-fluorenone (fn) ketyl in [Yb-III(DippForm)(2)(fn-O)] {DippForm = N,N-bis(2,6-diisopropylphenyl)formamidinate}, underwent reduction to the dianion ({C13H8}-O) upon single electron transfer from (SmI2)-I-II(thf)(2). The dianion was obtained as a decanuclear, deca-9-fluorenolato, tetraoxido mixed-oxidation-state samarium cage [Sm10O4{(C13H8)-O}(10)(thf)(10)], obtained after ligand redistribution. The structure is relevant to the deoxygenation of ketones by lanthanoid metals.

Item ID: 55034
Item Type: Article (Research - C1)
ISSN: 1099-0682
Keywords: cage compounds, ketones, cyclopentadienyl ligands, oxido ligands, redox chemistry
Funders: Australian Research Council (ARC)
Projects and Grants: ARC DP160101640
Date Deposited: 15 Aug 2018 07:42
FoR Codes: 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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