Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates

Werner, Daniel, Bayer, Uwe, Rad, Nazli E., Junk, Peter C., Deacon, Glen B., and Anwander, Reiner (2018) Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates. Dalton Transactions, 47 (17). pp. 5952-5955.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: http://doi.org/10.1039/c8dt00338f
 
1
2


Abstract

Homoleptic [La(Me(2)pz)(3)](n) (Me(2)pz = 3,5-dimethylpyrazolato) is a mu-eta(2):eta(5)-Me(2)pz coordination polymer with 12-coordinate La atoms in an unusual eta(5):eta(5) Me(2)pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce-4(Me(2)pz)(12)] featuring six different Me(2)pz coordination modes.

Item ID: 54445
Item Type: Article (Research - C1)
ISSN: 1477-9234
Funders: German Science Foundation (GSF), Australian Research Council (ARC)
Projects and Grants: GSF Grant AN 238/16-1, ARC grant DP16010640
Date Deposited: 04 Jul 2018 08:00
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 2
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page