Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates
Werner, Daniel, Bayer, Uwe, Rad, Nazli E., Junk, Peter C., Deacon, Glen B., and Anwander, Reiner (2018) Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates. Dalton Transactions, 47 (17). pp. 5952-5955.
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DOI: 10.1039/c8dt00338f
View at Publisher Website: http://doi.org/10.1039/c8dt00338f
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Abstract
Homoleptic [La(Me(2)pz)(3)](n) (Me(2)pz = 3,5-dimethylpyrazolato) is a mu-eta(2):eta(5)-Me(2)pz coordination polymer with 12-coordinate La atoms in an unusual eta(5):eta(5) Me(2)pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce-4(Me(2)pz)(12)] featuring six different Me(2)pz coordination modes.
| Item ID: | 54445 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1477-9234 |
| Funders: | German Science Foundation (GSF), Australian Research Council (ARC) |
| Projects and Grants: | GSF Grant AN 238/16-1, ARC grant DP16010640 |
| Date Deposited: | 04 Jul 2018 08:00 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3402 Inorganic chemistry > 340203 F-block chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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