Electroanalytical ventures at nanoscale interfaces between immiscible liquids

Arrigan, Damien W.M., and Liu, Yang (2016) Electroanalytical ventures at nanoscale interfaces between immiscible liquids. Annual Review of Analytical Chemistry, 9. pp. 145-161.

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Abstract

Ion transfer at the interface between immiscible electrolyte solutions offers many benefits to analytical chemistry, including the ability to detect nonredox active ionized analytes, to detect ions whose redox electrochemistry is accompanied by complications, and to separate ions based on electrocontrolled partition. Nanoscale miniaturization of such interfaces brings the benefits of enhanced mass transport, which in turn leads to improved analytical performance in areas such as sensitivity and limits of detection. This review discusses the development of such nanoscale interfaces between immiscible liquids and examines the analytical advances that have been made to date, including prospects for trace detection of ion concentrations.

Item ID: 53252
Item Type: Article (Research - C1)
ISSN: 1936-1335
Keywords: liquid-liquid, interface, nanopore, nanopipette, electrochemistry, electroanalysis
Funders: Australian Research Council (ARC)
Projects and Grants: ARC DP130102040
Date Deposited: 19 Apr 2018 22:04
FoR Codes: 03 CHEMICAL SCIENCES > 0301 Analytical Chemistry > 030102 Electroanalytical Chemistry @ 50%
03 CHEMICAL SCIENCES > 0306 Physical Chemistry (incl Structural) > 030604 Electrochemistry @ 50%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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