Visible-light photooxygenation of α-terpinene in a falling film microreactor
Shvydkiv, Oksana, Jähnisch, Klaus, Steinfeldt, Norbert, Yavorskyy, Alexander, and Oelgemöller, Michael (2018) Visible-light photooxygenation of α-terpinene in a falling film microreactor. Catalysis Today, 308. pp. 102-118.
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Abstract
The photooxygenation of α-terpinene was investigated in a falling film microreactor. The formation of microfilms and the flow operation allowed for a safe and controllable production of the bioactive endoperoxide ascaridole. Stepwise investigation of the process parameters resulted in the selective formation of ascaridole of up to 89% and a productivity of 2.5–3.2 mol L−1 h−1, respectively.
| Item ID: | 53076 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1873-4308 |
| Keywords: | falling film microreactor; photooxygenation; flow photochemistry; singlet oxygen; ascaridole; α-terpinene |
| Funders: | Science Foundation Ireland (SFI), Environmental Protection Agency (EPA) Ireland, Department of Environment, Heritage and Local Government (DEHLG), Australian Research Council (ARC) |
| Projects and Grants: | SFI 07/RFP/CHEF817, EPA 2008-ET-MS-2-S2, DEHLG 2008-S-ET-2, ARC DP130100794, ARC LE150100049 |
| Date Deposited: | 09 Apr 2018 23:26 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340503 Organic chemical synthesis @ 60% 34 CHEMICAL SCIENCES > 3405 Organic chemistry > 340505 Physical organic chemistry @ 40% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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