Synthesis and characterisation of heterobimetallic lanthanoid o-based cluster/cages

Andrews, Philip C., Bousrez, Guillaume, Junk, Peter C., Thielemann, Dominique T., and Werrett, Melissa V. (2017) Synthesis and characterisation of heterobimetallic lanthanoid o-based cluster/cages. European Journal of Inorganic Chemistry, 2017 (3). pp. 679-684.

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View at Publisher Website: https://doi.org/10.1002/ejic.201601264
 
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Abstract

The synthesis of new mono-and bimetallic lanthanoid cluster compounds is reported. The metal-to metal ratios of tetra-and pentanuclear clusters were determined by energy-dispersive X-ray spectroscopy (EDS). The EDS results show that, for an equal proportion of lanthanide salts introduced, different metal-to-metal ratios are achieved in the clusters. This ratio appears to be dependent on the size and electron density of the metal atoms. Studies realized the best conditions to achieve a 1:1 ratio.

Item ID: 50707
Item Type: Article (Research - C1)
ISSN: 1099-0682
Keywords: lanthanides, heterometallic complexes, cluster compounds, cage compounds, O ligands
Funders: Monash University, James Cook University, Australian Research Council (ARC)
Projects and Grants: ARC DP140102093
Date Deposited: 20 Sep 2017 11:12
FoR Codes: 03 CHEMICAL SCIENCES > 0306 Physical Chemistry (incl Structural) > 030606 Structural Chemistry and Spectroscopy @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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