Synthesis and characterisation of heterobimetallic lanthanoid o-based cluster/cages
Andrews, Philip C., Bousrez, Guillaume, Junk, Peter C., Thielemann, Dominique T., and Werrett, Melissa V. (2017) Synthesis and characterisation of heterobimetallic lanthanoid o-based cluster/cages. European Journal of Inorganic Chemistry, 2017 (3). pp. 679-684.
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Abstract
The synthesis of new mono-and bimetallic lanthanoid cluster compounds is reported. The metal-to metal ratios of tetra-and pentanuclear clusters were determined by energy-dispersive X-ray spectroscopy (EDS). The EDS results show that, for an equal proportion of lanthanide salts introduced, different metal-to-metal ratios are achieved in the clusters. This ratio appears to be dependent on the size and electron density of the metal atoms. Studies realized the best conditions to achieve a 1:1 ratio.
| Item ID: | 50707 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1099-0682 |
| Keywords: | lanthanides, heterometallic complexes, cluster compounds, cage compounds, O ligands |
| Funders: | Monash University, James Cook University, Australian Research Council (ARC) |
| Projects and Grants: | ARC DP140102093 |
| Date Deposited: | 20 Sep 2017 11:12 |
| FoR Codes: | 34 CHEMICAL SCIENCES > 3406 Physical chemistry > 340699 Physical chemistry not elsewhere classified @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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