Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(I) discrimination
Vasilescu, Ioana M., Bray, David J., Clegg, Jack K., Lindoy, Leonard F., Meehan, George V., and Wei, Gang (2006) Rational ligand design for metal ion recognition. Synthesis of a N-benzylated N2S3-donor macrocycle for enhanced silver(I) discrimination. Dalton Transactions , 2006 (43). pp. 5115-5117.
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DOI: 10.1039/b613636m
View at Publisher Website: http://dx.doi.org/10.1039/b613636m
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Abstract
Four previously documented ligand design strategies for achieving Ag(I) discrimination have been applied to the design of a new N-benzylated N2S3-donor macrocycle; the latter shows high selectivity for Ag(I) over Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Pb(II) in log K and bulk membrane transport studies.
| Item ID: | 4596 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1477-9234 |
| Keywords: | metal ion recognition; silver; macrocycle; synthesis |
| Date Deposited: | 15 Jun 2009 22:24 |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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