Oelgemöller, M., Lex, J., and Inoue, Y. (2002) Crystal structure of 1-Hydroxy-2'-methoxy-bicyclohexyl-1'-ene-2,3'-dione. Zeitschrift für Kristallographie - New Crystal Structures, 217 (2). pp. 201-202.

PDF (Published Version) - Published Version Restricted to Repository staff only

Abstract

The title compound was formed as a side-product via barium oxide/hydroxide mediated coupling of 1,2-cyclohexanedione, followed by in situ methylation with dimethyl sulfate. Recrystallization from n-hexane gave 11% of colorless prisms (mp 398 Κ - 400 Κ). Main product of this transformation was the methylated monoenolate of the dione in 54% yield.

Item ID:	44777
Item Type:	Article (Short Note)
ISSN:	2197-4578
Keywords:	structure determination; organic synthesis
Date Deposited:	04 Aug 2016 03:01
FoR Codes:	03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads:	Total: 10
	More Statistics