The synthesis and X-ray crystal structures of 1-D coordination polymers with Cu(II) bridging nodes and 'extended-reach' heterocyclic bridging ligands

Cottam, Justine R.A., Keene, F. Richard, and Steel, Peter J. (2015) The synthesis and X-ray crystal structures of 1-D coordination polymers with Cu(II) bridging nodes and 'extended-reach' heterocyclic bridging ligands. Supramolecular Chemistry, 27 (11-12). pp. 865-876.

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Abstract

A series of 1-D coordination polymers with varying Cu(II) bridging nodes were obtained by reactions of various copper salts with 'extended-reach' heterocyclic bridging ligands. Five of these have a 'necklace-type' topology, but differ in the nature of the Cu(II) linkages, some of which represent rare coordination motifs. In addition, cobalt(II) bromide was employed to generate a 'necklace-type' polymer similar to one of the copper(II) polymers.

Item ID: 41419
Item Type: Article (Research - C1)
ISSN: 1029-0478
Keywords: pyrazine; pyridine; Bisphenol; copper; cobalt; coordination polymer; crystal structure
Funders: Royal Society of New Zealand (RSNZ) Marsden Fund
Date Deposited: 26 Nov 2015 03:45
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970122 Expanding Knowledge in Philosophy and Religious Studies @ 100%
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