Lanthanoid induced C–F activation of all fluorine atoms of one CF3 group

Deacon, Glen B., Junk, Peter C., and Werner, Daniel (2015) Lanthanoid induced C–F activation of all fluorine atoms of one CF3 group. European Journal of Inorganic Chemistry, 2015 (9). pp. 1484-1489.

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Abstract

The lanthanum formamidinate complex [La(CF3Form)3] {CF3FormH = N,N'-bis(2-trifluoromethylphenyl)formamidine}, which has six La–F interactions in the solid-state structure, readily undergoes C–F activation of all fluorine atoms of one CF3 group to give LaF3, and two isomeric polytrifluoromethylphenyl-substituted polyamidines, one containing a 1,2,3,4-tetrahydroquinazoline heterocyclic core.

Item ID: 41130
Item Type: Article (Refereed Research - C1)
Keywords: C-F activation, fluorine, lanthanides, rare earths
ISSN: 1099-0682
Funders: Australian Research Council (ARC)
Projects and Grants: ARC Grant no. DP130100152
Date Deposited: 29 Oct 2015 03:26
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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