Structural characterization of γ-terpinene thin films using mass spectroscopy and X-Ray photoelectron spectroscopy
Ahmad, Jakaria, Bazaka, Kateryna, Whittle, Jason D., Michelmore, Andrew, and Jacob, Mohan V. (2015) Structural characterization of γ-terpinene thin films using mass spectroscopy and X-Ray photoelectron spectroscopy. Plasma Processes and Polymers, 12 (10). pp. 1085-1094.
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Abstract
Understanding the polymerization mechanism of a precursor is indispensable to enhance the requisite material properties. In situ mass spectroscopy and X-ray photoelectron spectroscopy is used in this study to understand the RF plasma polymerization of γ-terpinene. High-resolution mass spectra positive ion mass spectrometry data of the plasma phase demonstrates the presence of oligomeric species of the type [M+H]+ and [2M+H]+, where M represents a unit of the starting material. In addition, there is abundant fragmented species, with most dominant being [M+] (136 m/z), C10H13+ (133 m/z), C9H11+ (119 m/z), and C7H9+ (93 m/z). The results reported in this manuscript enables to comprehend the relationship between the degree of incorporation of oxygen and the rate of deposition with the input RF power.
Item ID: | 40274 |
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Item Type: | Article (Research - C1) |
ISSN: | 1612-8869 |
Keywords: | γ-terpinene; ion flux; mass spectroscopy; plasma polymerization; XPS |
Funders: | Australian Research Council (ARC), James Cook University (JCU) |
Projects and Grants: | DE130101550, ARC LE120100021 |
Date Deposited: | 25 Aug 2015 23:57 |
FoR Codes: | 09 ENGINEERING > 0912 Materials Engineering > 091209 Polymers and Plastics @ 100% |
SEO Codes: | 85 ENERGY > 8598 Environmentally Sustainable Energy Activities > 859899 Environmentally Sustainable Energy Activities not elsewhere classified @ 100% |
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