A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene
Deacon, G.B., Jaroschik, F., Junk, P.C., and Kelly, R.P. (2014) A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene. Chemical Communications, 50 (73). pp. 10655-10657.
![[img]](https://researchonline.jcu.edu.au/style/images/fileicons/application_pdf.png) |
PDF (Published Version)
- Published Version
Restricted to Repository staff only |
DOI: 10.1039/c4cc04427d
View at Publisher Website: http://dx.doi.org/10.1039/c4cc04427d
25
4
Abstract
The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.
| Item ID: | 37859 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1364-548X |
| Funders: | Australian Research Council (ARC), Université de Reims |
| Projects and Grants: | ARC Discovery grant DP130100152 |
| Date Deposited: | 26 Mar 2015 02:12 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
| Downloads: |
Total: 4 |
| More Statistics |
Actions (Repository Staff Only)
 |
Item Control Page |