Chiari, L., Duque, H.V., Jones, D.B., Thorn, P.A., Pettifer, Z., da Silva, G.B., Limão-Vieira, P., Duflot, D., Hubin-Franskin, M.-J., Delwiche, J., Blanco, F., Garcia, G., Lopes, M.C.A., Ratnavelu, K., White, R.D., and Brunger, M.J. (2014) Differential cross sections for intermediate-energy electron scattering from α-tetrahydrofurfuryl alcohol: excitation of electronic-states. Journal of Chemical Physics, 141. 024301. pp. 1-8.

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Abstract

We report on measurements of differential cross sections (DCSs) for electron impact excitation of a series of Rydberg electronic-states in α-tetrahydrofurfuryl alcohol (THFA). The energy range of these experiments was 20–50 eV, while the scattered electron was detected in the 10°–90° angular range. There are currently no other experimental data or theoretical computations against which we can directly compare the present measured results. Nonetheless, we are able to compare our THFA DCSs with earlier cross section measurements for Rydberg-state electronic excitation for tetrahydrofuran, a similar cyclic ether, from Do et al. [J. Chem. Phys.134, 144302 (2011)]. In addition, "rotationally averaged" elastic DCSs, calculated using our independent atom model with screened additivity rule correction approach are also reported. Those latter results give integral cross sections consistent with the optical theorem, and supercede those from the only previous study of Milosavljević et al. [Eur. Phys. J. D40, 107 (2006)].

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