Self-assembled bilayer films of ruthenium(II)/polypyridyl complexes through layer-by-layer deposition on nanostructured metal oxides

Hanson, Kenneth, Torelli, Daniel A., Vannucci, Aaron K., Brennaman, M. Kyle, Luo, Hanlin, Alibabaei, Leila, Song, Wenjing, Ashford, Dennis L., Norris, Michael R., Glasson, Christopher R.K., Concepcion, Javier J., and Meyer, Thomas J. (2012) Self-assembled bilayer films of ruthenium(II)/polypyridyl complexes through layer-by-layer deposition on nanostructured metal oxides. Angewandte Chemie International Edition, 51. pp. 12782-12785.

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Abstract

A "layer-by-layer" deposition of functionalized dyes/catalysts on the surfaces of nanocrystalline oxides is introduced. The strategy is general and offers considerable flexibility based on phosphonate- or carboxylate-binding groups with ZrIV as bridging ions. The resulting bilayer structures are capable of supporting rapid intra-layer energy and electron transfer.

Item ID: 33463
Item Type: Article (Research - C1)
ISSN: 1521-3773
Keywords: bilayers; chromophores; electron transfer; energy transfer; self-assembly
Funders: US Department of Energy (DOE), Army Research Office (ARO)
Projects and Grants: DOE Award DE-SC000129, DOE Award DE-SC0001298, DOE Award DE-FG02-06ER15788, ARO Grant W911NF-09-1- 0426, DOE Award DE-EE0003188
Date Deposited: 05 Jun 2014 00:03
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 50%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 50%
SEO Codes: 85 ENERGY > 8505 Renewable Energy > 850504 Solar-Photovoltaic Energy @ 50%
97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 50%
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