Self-assembled bilayers on indium−tin oxide (SAB-ITO) electrodes: a design for chromophore−catalyst photoanodes

Glasson, Christopher R.K., Song, Wenjing, Ashford, Dennis L., Vannucci, Aaron, Chen, Zuofeng, Concepcion, Javier J., Holland, Patrick L., and Meyer, Thomas J. (2012) Self-assembled bilayers on indium−tin oxide (SAB-ITO) electrodes: a design for chromophore−catalyst photoanodes. Inorganic Chemistry, 51 (16). pp. 8637-8639.

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Abstract

A novel approach for creating assemblies on metal oxide surfaces via the addition of a catalyst overlayer on a chomophore monolayer derivatized surface is described. It is based on the sequential self-assembly of a chromophore, [Ru(bpy)(4,4'-(PO3H2bpy)2)]2+, and oxidation catalyst, [Ru(bpy)(P2Mebim2py)OH2]2+, pair, resulting in a spatially separated chromophore−catalyst assembly.

Item ID: 33457
Item Type: Article (Research - C1)
ISSN: 1520-510X
Funders: US Department of Energy (DOE), Army Research Office (ARO)
Projects and Grants: DOE Award DESC0001011, ARO Grant W911NF-09-1- 0426, DOE Award DE-SC0001298
Date Deposited: 29 May 2014 04:31
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030207 Transition Metal Chemistry @ 50%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 50%
SEO Codes: 85 ENERGY > 8505 Renewable Energy > 850504 Solar-Photovoltaic Energy @ 50%
97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 50%
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