Microflow photochemistry—photodecarboxylations in microformats

Oelgemoeller, Michael, Gallagher, Sonia, and McCarthy, Kevin (2014) Microflow photochemistry—photodecarboxylations in microformats. Processes, 2 (1). pp. 158-166.

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Abstract

This article summarizes selected examples of intra- and intermolecular photodecarboxylations involving phthalimides in a commercially available dwell device. Compared to batch conditions in a larger chamber reactor, the investigated transformations in the microreactor furnished higher conversions and yields after significantly shorter reaction times. The product qualities were commonly higher under flow conditions thus avoiding the need for further purifications.

Item ID: 31121
Item Type: Article (Research - C1)
ISSN: 2227-9717
Keywords: photodecarboxylation; photochemistry; microreactor; flow chemistry
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Funders: Environmental Protection Agency, Department of Environment, Heritage and Local Government, Science Foundation Ireland, Australian Research Council
Projects and Grants: EPA, 2008-ET-MS- 2-S2, DEHLG, 2008-S-ET-2, SFI, 07/RFP/CHEF817, ARC, Discovery Project DP130100794
Date Deposited: 16 Mar 2014 22:49
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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