Microflow photochemistry—photodecarboxylations in microformats
Oelgemoeller, Michael, Gallagher, Sonia, and McCarthy, Kevin (2014) Microflow photochemistry—photodecarboxylations in microformats. Processes, 2 (1). pp. 158-166.
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Abstract
This article summarizes selected examples of intra- and intermolecular photodecarboxylations involving phthalimides in a commercially available dwell device. Compared to batch conditions in a larger chamber reactor, the investigated transformations in the microreactor furnished higher conversions and yields after significantly shorter reaction times. The product qualities were commonly higher under flow conditions thus avoiding the need for further purifications.
| Item ID: | 31121 |
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| Item Type: | Article (Research - C1) |
| ISSN: | 2227-9717 |
| Keywords: | photodecarboxylation; photochemistry; microreactor; flow chemistry |
| Additional Information: | All articles published by MDPI are made immediately available worldwide under an open access license. This means:everyone has free and unlimited access to the full-text of all articles published in MDPI journals, and everyone is free to re-use the published material if proper accreditation/citation of the original publication is given. This is an open access article published under a CC-BY 4.0 license. |
| Funders: | Environmental Protection Agency, Department of Environment, Heritage and Local Government, Science Foundation Ireland, Australian Research Council |
| Projects and Grants: | EPA, 2008-ET-MS- 2-S2, DEHLG, 2008-S-ET-2, SFI, 07/RFP/CHEF817, ARC, Discovery Project DP130100794 |
| Date Deposited: | 16 Mar 2014 22:49 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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