Novel rare earth quinolinolate complexes
Deacon, Glen B., Forsyth, Craig M., Junk, Peter C., Kynast, Ulrich, Meyer, Gerd, Moore, Joanne, Sierau, Jennyfer, and Urbatsch, Aron (2008) Novel rare earth quinolinolate complexes. Journal of Alloys and Compounds, 451 (1-2). pp. 436-439.
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Abstract
The reaction of europium 8-quinolinolate Eu(OQ)3 with calcium 8-quinolinolate, Ca(OQ)2, in the flux 1,2,4,5-tetramethylbenzene (TMB) at 210 °C yields the bimetallic [Eu2Ca(OQ)8], which is a linear tri-nuclear complex with two eight coordinate europium atoms flanking a six coordinate calcium atom bonded by six bridging phenolate oxygen atoms. A similar reaction between La(OQ)3 and Co(OQ)2 gave [LaCo2(OQ)7], in which two six coordinate cobalt atoms flank an eight coordinate lanthanum atom with six bridging phenolate oxygen atoms and a terminal OQ group.
| Item ID: | 30793 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1873-4669 |
| Keywords: | lanthanum; europium; calcium; cobalt; 8-quinolinolate (oxine); elevated temperature synthesis |
| Funders: | Australian Research Council (ARC) |
| Date Deposited: | 27 Feb 2014 06:10 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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