Rare earth thiocyanate complexes with 18-crown-6 co-ligands

Bakker, Jacinta M., Deacon, Glen B., and Junk, Peter C. (2013) Rare earth thiocyanate complexes with 18-crown-6 co-ligands. Polyhedron, 52 (Special Issue). pp. 560-564.

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Abstract

Reaction of [Ln(NCS)(3)(THF)(4)](2) or [Yb(NCS)(3)(THF)(4)] with 18-crown-6 yields the moisture-stable [Ln(NCS)(3)(18-crown-6)] (Ln = La, Nd, Dy, Yb) complexes. Although the Ln contraction does not affect the coordination number, the crown ether is decreasingly folded with decreasing ion size.

Item ID: 30429
Item Type: Article (Refereed Research - C1)
Keywords: lanthanoids; rare earths; thiocyanates; crown ethers
ISSN: 1873-3719
Date Deposited: 19 Mar 2014 05:32
FoR Codes: 03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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