Photodecarboxylative addition of carboxylates and α-keto carboxylates to phthalimides
Griesbeck, Axel G., and Oelgemoeller, Michael (1999) Photodecarboxylative addition of carboxylates and α-keto carboxylates to phthalimides. Synlett, 1999 (4). pp. 492-494.
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Abstract
Intermolecular photoinduced decarboxylative additions of formate and a series of alkyl carboxylates as well as α-keto carboxylates to N-substituted phthalimides 1a-c and N-phthaloyl amino acid esters 3a-i gave hydroxy phthalimidines 2a-2j, 6a, b, 9 and hydroxy phthalimidine methyl esters 4a-4i in moderate to high yields. Only in one case (adamantane derivative 10) imide-catalyzed decarboxylation to give the corresponding hydrocarbon was observed.
Item ID: | 29975 |
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Item Type: | Article (Research - C1) |
ISSN: | 1437-2096 |
Keywords: | photodecarboxylation, phthalimides, alkali metal carboxylates, α-keto carboxylates |
Funders: | Deutsche Forschungsgemeinschaft (DFG), Fonds der Chemischen Industrie, Degussa AG, Bayer AG, Merck KGaA |
Date Deposited: | 21 Mar 2014 22:18 |
FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 60% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40% |
SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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