Structural, CV and IR spectroscopic evidences for preorientation in PET-active phthalimido carboxylic acids

Oelgemoeller, Michael, Griesbeck, Axel G., Lex, Johann, Haeuseler, Andreas, Schmittel, Michael, Niki, Makiko, Hesek, Dusan, and Inoue, Yoshihisa (2001) Structural, CV and IR spectroscopic evidences for preorientation in PET-active phthalimido carboxylic acids. Organic Letters, 3 (11). pp. 1593-1596.

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Abstract

Hydrogen bond and potassium cation mediated preorientation were detected for phthalimido acetic acid and the corresponding acetate. Evidence for these phenomena came from X-ray structure analysis as well as cyclic voltammetric and IR spectroscopic measurements. These interactions rationalize the photoinduced electron transfer (PET) reactivity of the substrates in photodecarboxylation reactions.

Item ID: 29974
Item Type: Article (Research - C1)
ISSN: 1523-7052
Funders: Deutsche Forschungsgemeinschaft (DFG), Fonds der Chemischen Industrie, Volkswagenstiftung, Bayer AG, Merck KGaA
Date Deposited: 21 Mar 2014 22:12
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 30%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 70%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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