Regioselective photoacylation of substituted naphthoquinones

Schiel, C., Oelgemoeller, M., and Mattay, J. (1998) Regioselective photoacylation of substituted naphthoquinones. Journal of Information Recording, 24. pp. 257-260.

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Abstract

Photoreactions of aldehydes with quinones exhibit acylated hydroquinones in good yields. In the case of substituted naphthoquinones (pos. 5-8) two regioisomers are formed. However, lithium perchlorate as additive affords only one regioisomer. This effect is discussed on the basis of semiemperical calculations.

Item ID: 29903
Item Type: Article (Research - C1)
ISSN: 1025-6008
Date Deposited: 28 Oct 2013 02:45
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40%
03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 60%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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