Hydrogen bonding in phthalimido carboxylic acids: cyclic voltammetric study and correlation with photochemical reactivity, part 2, aliphatic and aromatic acids

Oelgemoeller, Michael, Haeuseler, Andreas, Schmittel, Michael, Griesbeck, Axel G., Lex, Johann, and Inoue, Yoshihisa (2002) Hydrogen bonding in phthalimido carboxylic acids: cyclic voltammetric study and correlation with photochemical reactivity, part 2, aliphatic and aromatic acids. Journal of the Chemical Society, Perkin Transactions 2, 2002 (3). pp. 676-686.

[img] PDF (Published Version) - Published Version
Restricted to Repository staff only

View at Publisher Website: http://dx.doi.org/10.1039/B105860F
 
15
4


Abstract

Cyclic voltammetry was applied as a useful tool for the detection and semiquantitative assessment of hydrogen bonding in phthalimidoalkyl and aryl carboxylic acids in solution. Both intra- and intermolecular hydrogen bonding could be detected and were assigned on the basis of base (DBU), acid (trifluoromethanesulfonic acid), solvent (MeCN vs. DMF), concentration and scan rate effects, as well as multisweep experiments. The observation of intramolecular hydrogen bonding neatly correlates with the reactivity pattern of the corresponding phthalimido carboxylic acids in photodecarboxylation reactions.

Item ID: 29879
Item Type: Article (Research - C1)
ISSN: 1364-5471
Date Deposited: 24 Oct 2013 06:04
FoR Codes: 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 100%
SEO Codes: 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
Downloads: Total: 4
More Statistics

Actions (Repository Staff Only)

Item Control Page Item Control Page