Microflow photochemistry: UVC-induced [2 + 2]-photoadditions to furanone in a microcapillary reactor
Bachollet, Sylvestre, Terao, Kimitada, Aida, Shin, Nishiyama, Yasuhiro, Kakiuchi, Kiyomi, and Oelgemoeller, Michael (2013) Microflow photochemistry: UVC-induced [2 + 2]-photoadditions to furanone in a microcapillary reactor. Beilstein Journal of Organic Chemistry, 9. pp. 2015-2021.
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Abstract
[2 + 2]-Cycloadditions of cyclopentene and 2,3-dimethylbut-2-ene to furanone were investigated under continuous-flow conditions. Irradiations were conducted in a FEP-microcapillary module which was placed in a Rayonet chamber photoreactor equipped with low wattage UVC-lamps. Conversion rates and isolated yields were compared to analogue batch reactions in a quartz test tube. In all cases examined, the microcapillary reactor furnished faster conversions and improved product qualities.
| Item ID: | 29712 |
|---|---|
| Item Type: | Article (Research - C1) |
| ISSN: | 1860-5397 |
| Keywords: | cycloaddition; cyclobutane; flow chemistry; furanone; microflow chemistry; photochemistry |
| Additional Information: | This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc). |
| Funders: | Australian Research Council (ARC) |
| Projects and Grants: | Discovery Project, DP130100794 |
| Date Deposited: | 08 Oct 2013 02:26 |
| FoR Codes: | 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030503 Organic Chemical Synthesis @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030505 Physical Organic Chemistry @ 40% 03 CHEMICAL SCIENCES > 0305 Organic Chemistry > 030504 Organic Green Chemistry @ 20% |
| SEO Codes: | 97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100% |
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