Dinitrogen reduction and C[BOND]H activation by the divalent organoneodymium complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]

Jaroschik, Florian, Momin, Aurélien, Nief, François, Le Goff, Xavier-Frédéric, Deacon, Glen, and Junk, Peter C. (2009) Dinitrogen reduction and C[BOND]H activation by the divalent organoneodymium complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]. Angewandte Chemie International Edition, 48 (6). pp. 1117-1121.

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DOI: 10.1002/anie.200804934

View at Publisher Website: http://dx.doi.org/10.1002/anie.200804934

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Abstract

Highly reactive: The first divalent organoneodymium complex has been isolated and characterized by X-ray crystallography. It reacts immediately with all common aromatic and ethereal solvents, reduces dinitrogen to form an isolable dinitrogen complex, and undergoes C[BOND]H activation of a ligand tert-butyl group to form a crystallizable "tuck-in" complex (see scheme).


Item ID:	29696
Item Type:	Article (Research - C1)
ISSN:	1521-3773
Keywords:	C-H activation, dinitrogen activation, dysprosium, neodymium, sandwich complexes
Funders:	Ecole Polytechnique, CNRS, Australian Research Council (ARC)
Date Deposited:	02 Oct 2013 10:34
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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