Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy

Andrews, Philip C., Gee, William J., Junk, Peter C., Krautscheid, Harald, and MacLellan, Jonathan G. (2010) Monitoring the stepwise assembly of a 3-D framework from a supramolecular lanthanoid synthon by in situ infrared spectroscopy. Chemical Communications, 46 (32). pp. 5948-5950.

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DOI: 10.1039/c0cc00949k

View at Publisher Website: http://dx.doi.org/10.1039/c0cc00949k

Abstract

Construction of a 3-D supramolecular network from [Ln(cpb)3(H2O)2] (Ln = Nd, Tb; Hcpb = 1-(4-cyanophenyl)-1,3-butanedione) by sequential displacement of a coordinated water by DMF, dimerisation by reciprocal hydrogen bonding in solution and π–π stacking and interdigitation of nitriles has been monitored by in situ fourier transform infrared spectroscopy.


Item ID:	29678
Item Type:	Article (Research - C1)
ISSN:	1364-548X
Keywords:	molecular tectonics; hydrogen-bonds; networks; crystals; packing
Date Deposited:	02 Oct 2013 10:34
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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