Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II)compounds?

Wiecko, Michal, Deacon, Glen B., and Junk, Peter C. (2010) Organolanthanoid-halide synthons - a new general route to monofunctionalized lanthanoid(II)compounds? Chemical Communications, 46 (28). pp. 5076-5078.

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DOI: 10.1039/c0cc01317j

View at Publisher Website: http://dx.doi.org/10.1039/c0cc01317j

Abstract

New EuII and YbII complexes [Ln(Ph2pz)I(thf)4] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh2pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated YbII/YbIII complex [{Yb(dme)4}{YbPh4(dme)}2] has been isolated.


Item ID:	29677
Item Type:	Article (Research - C1)
ISSN:	1364-548X
Keywords:	heavy grignard-reagents; crystal-structures; structural-characterization; organometallic compounds; metal-compounds; lanthanide; complexes; chemistry; reactivity; europium(II)
Funders:	Australian Research Council (ARC), Deutsche Forschungsgemeinschaft (DFG)
Projects and Grants:	Australian Research Council (ARC) DP0984775
Date Deposited:	02 Oct 2013 10:34
FoR Codes:	03 CHEMICAL SCIENCES > 0302 Inorganic Chemistry > 030202 f-Block Chemistry @ 100%
SEO Codes:	97 EXPANDING KNOWLEDGE > 970103 Expanding Knowledge in the Chemical Sciences @ 100%
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